1.

Acid-catalysed hydration of alkenes except ethene leads to the formation ofA. primary alcoholB. secondary or tertiary alcoholsC. mixture of primary and secondary alcoholsD. mixture of secondary and tertiary alcohols

Answer» Correct Answer - B
Ethene gives `1^@` alcohol (ethanol) , propene gives `2^@` alcohol while 2-methylpropene gives `3^@` alcohol.
`underset"Ethene"(CH_2=CH_2)underset((ii)H_3O^+)overset((i)Conc. H_2SO_4)to underset"Ethanol"(CH_3CH_2OH)`
`underset"Propene"(CH_3-CH=CH_2)underset((ii)H_3O^+)overset((i)Conc. H_2SO_4)to underset(2^@ "Alcohol")(CH_3-CHOH-CH_3)`
`underset"2-Methylpropene"(CH_3-oversetoverset(CH_3)|C=CH_2)underset((ii)H_3O^+)overset(Conc. H_2SO_4)to underset(3^@ "Alcohol")((CH_3)_3COH)`
Thus , either `2^@` or `3^@` alcohol is formed.


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