1.

Addition of CdCl2 to the crystal of AgCl will produce schottky defect, but the same is not produced when NaCl crystal are added, Why?

Answer»

The replacement of one Ag+ ion with Cd+ ion necessitates the removal of other Ag+ ion from the lattice to maintain the electrical neutrality of the crystal. But in case of NaCl, Na+ and Ag+ both are monovalent. 



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