1.

Addition of excess aqueous ammonia to a pink coloured aqueous solution of MCl2.H2O(x) and NH4Cl gives an octahedral complex Y in the presence of air. In aqueous solution, complex Y behaves as 1:3 electrolyte. The reaction of X with excess HCl at room temperature results in the formation of a blue coloured complex Z. The calculated spin only magnetic moment of X and Z is 3.87 B.M., whereas it is zero for complex Y.Among the following options, which statemet(s) is (are) correct?

Answer»

Addition of excess aqueous ammonia to a pink coloured aqueous solution of MCl2.H2O(x) and NH4Cl gives an octahedral complex Y in the presence of air. In aqueous solution, complex Y behaves as 1:3 electrolyte. The reaction of X with excess HCl at room temperature results in the formation of a blue coloured complex Z. The calculated spin only magnetic moment of X and Z is 3.87 B.M., whereas it is zero for complex Y.

Among the following options, which statemet(s) is (are) correct?





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