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All titration which involves the direct titration of Iodine with a reducing agent are grouped under lodimetry. Iodimetry is employed to determine the strength of reducing agent such as sodium thio sulphate I_(2) + 2Na_(2)S_(2)O_(3) rarr 2I^(-)+S_(4)O_(6)^(-) If iodine is liberated as a result of chemical reaction involving oxidation of an idodide ion by a strong oxidizing agent in neutral or acidic medium the liberated iodine is then titrated with reducing agent. This titration is called lodometry. Todometry is used to estimate the strength of oxidizing agent. For example the estimation of Cu^(++)with thiosulphate. Cu^(+ +) +I^(-) Cu_(2)I_(2)+I_(2) , I_(2)+S_(2)O_(3)^(-) rarrS_(4)O_(6)^(-) +I^(-) Starch used as indicator near the end point which form blue colour complex with I_(3)^(-) . The blue colour disappears when10 mL of H_2O_2solution on treatment with KI and titration of liberated I_2required 10 mL of 1 Nhypo . Thus H_2O_2 is :

Answer» <html><body><p>1 N<br/>5.6 volume <br/>`<a href="https://interviewquestions.tuteehub.com/tag/17-278001" style="font-weight:bold;" target="_blank" title="Click to know more about 17">17</a> gL^(-1)`<br/>All are correct </p>Solution :No. ofmilli equivalent of `H_(2)SO_(<a href="https://interviewquestions.tuteehub.com/tag/4-311707" style="font-weight:bold;" target="_blank" title="Click to know more about 4">4</a>)=` <br/> No. of milli equivalents of hypo <br/> `10xx N = <a href="https://interviewquestions.tuteehub.com/tag/10-261113" style="font-weight:bold;" target="_blank" title="Click to know more about 10">10</a> xx 1 , N = 1N` <br/>Volume strength =` 5.6 xx N = 5.6 ` <br/> `N = <a href="https://interviewquestions.tuteehub.com/tag/w-729065" style="font-weight:bold;" target="_blank" title="Click to know more about W">W</a>/(CrEW)<a href="https://interviewquestions.tuteehub.com/tag/xx1-1463705" style="font-weight:bold;" target="_blank" title="Click to know more about XX1">XX1</a>` <br/> `W = N xx GEW = 1 xx 17 = 17 g `.lit</body></html>


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