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Amino grup is ortho, para-directing for aromatic electrophilic substitution, On nitration of aniline, a good amount of m-nitroaniline is obtained. This is due to : |
Answer» <html><body><p>in nitration <a href="https://interviewquestions.tuteehub.com/tag/mixture-1098735" style="font-weight:bold;" target="_blank" title="Click to know more about MIXTURE">MIXTURE</a>, ortho-, para-activity of `-NH_(2)` <a href="https://interviewquestions.tuteehub.com/tag/group-1013370" style="font-weight:bold;" target="_blank" title="Click to know more about GROUP">GROUP</a> is <a href="https://interviewquestions.tuteehub.com/tag/completely-409686" style="font-weight:bold;" target="_blank" title="Click to know more about COMPLETELY">COMPLETELY</a> <a href="https://interviewquestions.tuteehub.com/tag/lost-537630" style="font-weight:bold;" target="_blank" title="Click to know more about LOST">LOST</a><br/>`-NH_(2)" bencomes " NH_(3)^(+),"which is m-directing"`<br/>`-NH_(2)" bencomes "-NH^(+)SO__(<a href="https://interviewquestions.tuteehub.com/tag/4-311707" style="font-weight:bold;" target="_blank" title="Click to know more about 4">4</a>)^(-), "which is m-directing"` <br/>`-NH_(2)" bencomes "-NH^(-)SO_(4)^(-)," which is m-directing "`</p>Answer :b</body></html> | |