1.

Among the following, the correct statement(s) is(are)A. `Al(CH_(3))_(3)` has the three-centre two-electron bonds in its dimeric strucutresB. `BH_(3)` has the three-centre two-electrons bonds in its dimeric structureC. the Lewis acidity of `BCl_(3)` is greater than that of `AlCl_(3)`D. `AlCl_(3)` has the three-centre two-electron bonds in its dimeric structure.

Answer» Correct Answer - A::B::C
In dimeric structure of `AlCl_(3)`, the bridged Cl forms a convalent bond with one Cl atom and coordinate bond with the other. As such it does have a `3c-3c` bond as in `Al_(2)(CH_(3))_(6)` and `B_(2)H_(6)`. The option (d) is not correct while all other options (a,b,c) are correct.


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