1.

Among the following which one is a wrong statement ?

Answer»

`SeF_(4)` and `CH_(4)` have same shape
`I_(3)^(+)` has bent GEOMETRY
`PH_(5)` and `BiCl_(5)` do not exist
`p pi - d pi` bonds are present in `SO_(2)`

Solution :(A) `SeF_(4)-sp^(3)d, Ip = 1`, shape = see - saw
`CH_(4)-sp^(3), Ip=0`, shape = TETRAHEDRAL
(B) `I_(3)^(+)-sp^(3), Ip=2`, shape = bent / anglar
(C ) `PH_(5)=` d-orbital contraction absent
`BiCl_(5)=` due to inert pair EFFECT
(`Bi^(+5)` act as `OA, Cl^(-)` act as RA)
(D)`SO_(2):O=S=O`
`P pi-d pi, P pi - P pi`both type bonds are present


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