1.

Amount of oxalic acid present in a solution can be determined by its titration with `KMnO_(4)` solution in the presence of `H_(2)SO_(4)` . The titration gives unsatisfactory rasult when carried out the presence of HCl because HClA. reducs permanganate to `Mn^(2+)`B. oxidises oxalic acid to carbon dioxide and waterC. gets oxidized by oxalic acid to chlorineD. furnishes `H^(+)` ions in addition to those from oxalic acid.

Answer» Correct Answer - A
In presence of `H_(2)SO_(4), KMnO_(4)` oxidises oxalic acid to `CO_(2)` .In presence of HCl, `KMnO_(4)` not only oxidises oxalic acid but also oxidises HCl to `Cl_(2)` and itself it is reduced to `Mn^(2+)`


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