1.

An alcohol (A) on treatment with conc. H_(2)SO_(4) gave an alkene (B). The compound (B), on reacting with Br_(2) water and subsequent dehydrobomination with NaNH_(2) produced a compound (C). The compound (C) with dil. H_(2)SO_(4) in presence (D) can also be obtained by oxidation of A by acifified KMnO_(4) or from dry heating of calcium acetate. Calculate the mass of 0.1 mol of D in gms. Round off your answer to next nearest integer.

Answer»


Solution :`CA(CH_(3)COO)_(2)overset(Delta)RARR underset(M.W=58)(CH_(3)-overset(O)overset(||)(C)-CH_(3))+ CaCO_(3)darr`


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