1.

An alcohol on oxidation is found to give CH_(3)COOH and CH_(3)CH_(2)COOH. The structure of the alcohol is

Answer»

`CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)OH`
`(CH_(3))_(2)C(OH)CH_(2)CH_(3)`
`CH_(3)CH_(2)CH_(2)CH(OH)CH_(3)`
`CH_(3)CH(OH)CH_(2)CH_(2)CH_(3)`

SOLUTION :SINCE the alcohol FORMS a mixture of acids, each with LESSER number of carbon atoms. This suggests the presence of secondary ALCOHOLIC group.
`underset(A 2^(@) alcohol")(CH_(3)-CH_(2)-CH_(2)-overset(OH)overset(|)(CH)-CH_(3) overset([O])rarr)`
`CH_(3)-CH_(2)-CH_(2)-overset(O)overset(||)(C)-CH_(3) overset([O])rarr CH_(3)CH_(2)COOH+CH_(3)COOH`


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