1.

An alkane C_(6)H_(14) gives two monochloro derivatives on chlorination. Its possible structure is

Answer»

`CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)CH_(3)`
`CH_(3)-UNDERSET(CH_(3))underset(|)(C)H-CH_(2)CH_(2)CH_(3)`
`CH_(3)-underset(CH_(2)CH_(3))underset(|)(C)H-CH_(2)CH_(3)`
`CH_(3)-OVERSET(CH_(3))overset(|)(C)H-overset(CH_(3))overset(|)(C)H-CH_(3)`

Solution :`CH_(3)-overset(CH_(3))overset(|)(C)H-overset(CH_(3))overset(|)(C)H-CH_(3)overset(Cl_(2))to CH_(3)-overset(CH_(3))overset(|)(C)H-overset(CH_(3))overset(|)underset(CL)underset(|)(C)-CH_(3)+ClCH_(2)-overset(CH_(3))overset(|)(C)H-overset(CH_(3))overset(|)(C)H-CH_(3)`


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