1.

An alkyl bromide (X) reacts with sodium in ether to form 4,5-diethyloctane, the compound 'X' is

Answer»

`CH_3(CH_2)_3 Br`
`CH_3(CH_2)Br`
`CH_3(CH_2)_3CH(Br)CH_3`
`CH_3-(CH_2)_2-CH(Br)-CH_2CH_3`

Solution :`2CH_3-(CH_2)_2-oversetoverset(""CH_2CH_3)|CH-Br+2Na UNDERSET"(WURTZ reaction)"OVERSET"Dry ether"tounderset"4,5-Diethyloctane"(overset1CH_3-overset"2-3"((CH_2))_2-oversetoverset(""CH_3CH_2)|underset4" CH"-oversetoverset("" CH_2CH_3)|underset5" CH"-overset"6-7"(("" CH_2)_2)-overset8CH_3-2NaBr)`
Thus , option (d) is CORRECT.


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