1.

An aqueous solution of metal ion M_(1) reacts separately with reagents Q and R in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution of anotherr metal ion M_(2) always forms tetrahedral complex with these reagents. Aqueous solution of M_(2) on reaction with reagent S gives white precipitate which dissolves in excess of S. The reactions are summarized in the scheme given ahead. SCHEME: Tetrahedral overset(Q)underset("excess")larr M_(1)overset(R)underset("excess")rarr Square planar {:("Tetrahedral"overset(Q)underset("excess")larrM_(2)overset(R)underset("excess")rarr"Tetrahedral"),(""darrS."stoichiometric amount"),("""White ppt" overset(S)underset("excess")rarr."Precipitate dissolves"):} M_(1),Q and R, respectively are:

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`ZN^(2+),KCN` and `HCI`
`Ni^(2+),HCI` and KCN
`Cd^(2+),KCN` and HCI
`CO^(2+),HCI` and KCN

Answer :B


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