1.

An element A in a compound AB has oxidationnumber -n. IT is oxidized by Cr_(2)O_(7)^(2-) in acid medium. In the experiment 1.68xx10^(-3) moles of K_(2)Cr_(2)O_(7) was usedfor 3.36xx10^(-3) moles of AB. The new oxidation number of A after oxidation is

Answer»

3
3 - n
n - 3
`+n`

Solution :`n= (1.68xx10^(-3))/(6xx 3.2 xx10^(-3))`
`A^(n-)OVERSET(+n)rarrA^(X)` `1/(x+n)` moles `A^(n-),`
`overset(+12)(Cr_2)overset(2-)(O_7)overset((6))rarr2cv^(3+)`
`-=1/6` moles `Cr_(2)O_(7)^(2-)=1.68 xx10^(-3)`
`(x+n)Cr_(2)O_(7)^(2-)-=6A^(n-)`
`1.6 8810^(-3)""?`
`=(1.68 xx10^(-3)xx6)/(x+n)=3.26xx10^(-3)`
x = 3 - n


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