1.

An ionic hydride of an alkali metal has significant covalent character and is almost unreactive towards oxygen and chlorine. This is used in the synthesis of other useful hydrides . Write the formula of this hydride . Write its reaction with Al_(2)Cl_(6).

Answer»

SOLUTION :Since an ionic hydride of an alkali metal has significant covalent character, therefore, the hydride will be of the smallest alkali metal (Li) , i.e., LIH, Since LiH is very stable, therefore, it is ALMOST UNREACTIVE towards `O_(2) and Cl_(2)`
Itreacts with `Al_(2)Cl_(6)` to form lithium aluminium hydride.
`8LiH + Al_(2)Cl_(6) to 2LiAlH_(4) + 6LiCl`.


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