1.

An organic compound (P) with molecular formula C_(6)H_(8)O_(4) is stable to heat but hydrolyse to (Q) and MeOH by NaOH follwed by acidification. (Q) on strong heating gives (R) which with Red P/HI gives ethane. Compound (P) is:

Answer»

`CH_(3)-underset(O)underset(||)(C)-O-underset(O)underset(||)(C)-OC_(2)H_(5)`
`CH_(3)-underset(O)underset(||)(C)-underset(O)underset(||)(C)-underset(O)underset(||)(C)-OCH_(3)`

SOLUTION :(P) on HYDROLYSIS gives propanedioic aci and methanol. Propanedioic acid on strong heating gives acetic acid which when reduced with Red P/HI gives ethane.


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