1.

An organic compound with moleular formula, C_(2)H_(6)O_(2) evolves H_(2) when treated with sodium metal and gives two moles of formaldehyde on oxidation with HIO_(4). The compound is

Answer»

Acetic acid
Methyl acetate
Ethylene glycol
Ethyl alcohol

Solution : `C_(2)H_(6)O_(2)` is
`{:(CH_(2)OH""CH_(2)ONA ""CH_(2)OH),("|"overset(Na)rarr"|" +(1)/(2)H_(2)"|" + HIO_(4) rarr2HCHO+HIO_(3)+H_(2)O),(CH_(2)OH ""CH_(2)OH""CH_(2)OH),():}`


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