1.

An organic compound with the formula C_6 H_(12) O_6 forms a yellow crystalline solid with phenylhydrazine and gives a mixture of sorbitol and mannitol when reduced with sodium. Which among the following could be the compound?

Answer»

fructose
glucose
mannose
sucrose

Solution :As `C_(6)H_(12)O_(6)` forms a crystalline osazone with phenylhydrazine, it must be an aldohexose or KETOHEXOSE. As the compound on reduction with Na gives sorbitol and MANNITOL, the given compound is fructose.
`UNDERSET("Fructose")({:(""CH_(2)OH),("|"),(""C=O),("|"),(HO-C-H),("|"),(2H-C-OH ),("|"),(" "H-C-OH),("|"),(""CH_(2)OH):})overset(+4[H])to""underset("Methanol")({:(""CH_(2)OH),("|"),(HO-C-H),("|"),(HO-C-H),("|"),(" "H-C-OH),("|"),(" "H-C-H),("|"),(""CH_(2)OH):}) + "" underset("Sorbitol")({:(""CH_(2)OH),("|"),(" "H-C- H),("|"),(HO-C-H),("|"),(" "H-C-OH),("|"),(" "H-C-OH),("|"),(""CH_(2)OH):})`


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