1.

An queous solution of a substance gives a white precipitate on treating with dilute hydrochloric acid which dissolves on heating. When hydrogen sulphide is passed through the hot solution, a black precipitate is obtained. The substance is :

Answer»

`Hg^(2+)` salt
`Cr^(3+)` salt
`Ag^(+)` salt
`Pb^(2+)` salt

Solution :`Hg^(2+)` salt GIVES white precipitate with dilute HCl.
`HgO + 2HCl rarr UNDERSET(("White ppt"))(HgCl_(2)) + H_(2)O`
`HgCl_(2) + H_(2)S rarr underset(("Black ppt"))(HgS) + 2HCl`


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