1.

Apart from tetrahedral geometry, another possible geometry for CH_(4) isSquare planar With four H atoms at the corners of the square and C atom at its centre. Explain why CH_(4) is not square planar?

Answer»

SOLUTION :ELECTRONIC configuration of carbon atom: C : `SIGMA1S^(2)2s^(2)2p^(2)`
In the excited state, the orbital picture of carbon can be represented as:

Hence. carbon atom undergoes `sp^(3)` hybridisation in `CH_(4)` molecule and takes tetrahedral shape.

ror a SQUARE planar shape, the hybridisation of the central atom has to be `dsp^(3)`. However, an atom of carbon does not have d-orbitals to undergo `dsp^(3)` hybridisation. Hence, the structure of `CH_(4)`is tetrahedral.


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