1.

Arrange the following acid in order of increasing acidity

Answer»

`I gt II gt III gt IV`
`II gt III gt I gt IV`
`III gt II gt IV gt I`
`III gt IV gt II gt I`

Solution :Due to ORTHO effect, `o-` nitrobenzoic acid is the strongest acid. Further SINCE electron-with drawing group such as `NO_(2)` INCREASES while the acid strength w.r.t. parent acid. `:.` the over all acidity increases in the order
`C lt D lt B lt A`


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