1.

Arrange the following alcohols in the decreasing order of reactivity towards (a) Lucas reagent Sodium metal (1) 1-Butano1 (2) sodium metal (3) 2-Methy1-2-propanol.

Answer» (a) `3 gt 2 gt 1`[with Lucas reagent (anhydrous `ZnC1_2 + conc. HC1 (1 : 1), 3^@ gt 2 ^@ gt 1^@` alcohol].
(b) `1 gt 2 gt 3`(with sodium metal reactivity is `1^@ gt 2^@ gt 3^@` alcohol).


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