1.

Arrange the following compounds in increasing order of acidity. (i)CH_(3) CH (Br) CH_(2) COOH (ii)CH_(3) CH_(2) CH (Br) COOH (iii)CH_(3) CH_(2)C (Br)_(2) COOH (iv)CH_(2) Br CH_(2) CH_(2) COOH

Answer»

SOLUTION :` square ` Br group causes polarity .
` square ` As the distance between Br and COOH increases ,
` square ` Order of acidity : ` III gt II gt I gt IV `
[Hint:INDUCTIVE effect DECREASES due to polarity ] .


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