1.

Arrange the following in decreasing order of their boiling points (A) n-butane , (B)-2-methylbutane , (C ) n-pentane, (D)2,2-dimethylpropane

Answer»

A GT B gt C gt D
B gt C gt D gt A
D gt C gtB gt A
C gt B gt D gt A

Solution :Boiling POINTS decrease with INCREASE in branching and with decrease in total number of carbon atoms. Thus, boiling points decrease in the order : C (n-pentane ) gt B (2-methylbutane ) gt D (2,2-dimethylbuane ) gt n-butane (A)


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