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Arrange the following in order of increasing;(A) Dipole moment of H2O, H2S , BF3 (B) Covalent character of LiCl, LiBr , LiI (C) Covalent character of NaCl , MgCl2 , AlCl3 |
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Answer» (A) BF3 is a symmetrical molecule. It has zero dipole moment. Oxygen being more electronegative than S, bond moment of O-H is more than S-H. So the dipole moment are in the order of BF3<H2S<H2O. (B) The anion size in increasing order is Cl-<Br-<I-. Hence LiCl is least covalent than LiI . The order is LiCl<LiBr<LiI. (C) Cation size in decreasing order is Na+ >Mg2+ >Al3+. Thus Al3+ ion has maximum polarization effect and Na+ ion has least. Thus the covalent order is NaCl <MgCl2<AlCl3 |
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