1.

Assertion (A) : In the dissociation of PCl_(5) at constant pressure and temperature addition of helium at equilibrium increases the dissociation of PCl_(5).

Answer»

Both A and Rare trueand R is the correct explanation of A.
Both A and Rare truebutR is NOTTHE correct explanation of A.
A is TRUE but R is false.
Both A and R are false.

Solution :Correct R. To keep pressure constant, ADDITION of helium is ACCOMPANIED by increase in volume of the reaction mixture.


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