1.

Assertion (A): In the resonance structure of aniline the NH_(2) group donate electron pair of nitrogen to the benene ring Reason (R ): In aniline artho and para position of -NH_(2) group possess negative charge

Answer»

Statement (A) and Reason (R ) both are RIGHT. Statement (R ) is correct explanation of statement (A)
Statement (A) and Reason (R ) both are right, but (R ) is not correct explanation of statement (A)
Both Statement (A) and (R ) are wrong
Statement (A) is right but statement (R ) is wrong

Solution :
In amino group hydrogen is attach with N. The electronegativity of nitrogen is more than hydrogen. So the non-bonding ELECTRON pair on nitrogen MOVE TOWARDS the aromatic contain so electron pair of N SHIFT in benzene ring.


Discussion

No Comment Found