1.

Assertion (A) : Toluene on Friedal Crafts methylation gives o-and p-xylene. Reason (R) : CH_(3) group bonded to benzene ring increases electron density at o-and p-position.

Answer»

Both A and R are correct and R is the correct explanation of A.
Both A and R are correct and R is not the correct explanation of A.
Both A and R are not correct.
A is not correct but R is correct.

Solution :Toluene has `-CH_(3)` group ATTACHED to benzene RING.
`CH_(30` group is electron withdrawing group which activates benzene ring due to hyper-conjugation effect, and increases electron density on ortho and parapositions for the attack of electrophiles.


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