1.

Assertion . The bond anlge of PBr_(3) is greater than that of PH_(3) but bond angle of NBr_(3) is less than that of NH_(3). Reason .Electronegativity of phosphorus atom is less thanthat of nitrogen .

Answer»

If both assertion and reason are correct, and reason is the correct explanation of the assertion.
If both assertion and reason are correct , but reason is not the correct explanation of the assertion.
If assertion is correct, but reason is incorrect .
If both assertion and reason are incorrect.

Solution :Correct explanation. The TRUTH of assertion is not due to DIFFERENCE in the electronegativities of N
and P but due to difference in electronegativity of
H and Br (in `NH_(3) and NBr_(3))` and due to reaonance
in ` PBr_(3)` but no resonance in `PH_(3)`


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