1.

Assign suitable reason for the following:BiH3 is the strongest reducing agent among all the hydrides of group 15 elements.H2O is a liquid but H2S is a gas.O3 acts as a powerful oxidising agent.

Answer»
  1. Among 15th group elements, Bi is of the largest size and hence Bi-H bond is the longest.
    As a result BiH3 acts as the strongest reducing agent because of easy formation of H2.
  2. Due to intermolecular hydrogen bonding, H2O is a liquid whereas H2S which does not have such bonds exist as a gas.
  3. O3 gets dissociated to give nascent oxygen which is responsible for its strong oxidising action
    O → O + ‘O’


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