1.

Assuming 2s - 2p mixing is not operative , the paramagnetic species among the following is

Answer»

`Be_(2)`
`B_(2)`
`C_(2)`
`N_(2)`

Solution :If `2S - 2p ` MIXING is not operative , then molecular
orbitals may be ARRANGED in ORDER of energy as follows :
`sigma (1s), sigma^(**) (1s), sigma(2s), sigma^(**) (2s), sigma(2p_(z)), PI(2p_(x))`
`= (2p_(y)), pi^(**) (2p_(x)) = pi^(**) (2p_(y)), sigma^(**) (2p_(z))`
Applying this configuration , `Be_(2), B_(2) and N_(2)`will
be diamgnetic but `C_(2)` will be paramagnetic .


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