1.

Balance the equation: S + HNO3→ H2SO4 + NO2 + H2O

Answer»

Balanced equation: S + 6HNO3→ H2SO4 + 6NO2 + 2H2

Step 1: Write the unbalanced equation

S + HNO3→ H2SO4 + NO2 + H2O

Step 2: Compare the number of atoms of reactants with the number of atoms of products.

Reactants (left side)Products (right side)
ElementNumber of atomsNumber of atoms
S11
H14
O37
N11

Step 3: Now, first let us consider nitrogen atom. If we multiply 6 in the reactant (HNO3) and product (in NO2), we will get the equal number of atoms.

No. of atoms of nitrogenReactant (in HNO3)Product (in NO2)
Initially11
To balance1 x 6 = 61 x 6 = 6

Step 4: Write the resulting equation:

S + 6HNO3→ H2SO4 + 6NO2 + H2O

Step 5: Now check whether the equation is balanced or not by comparing the atoms

Reactants (left side)Products (right side)
ElementNumber of atomsNumber of atoms
S11
H64
O1817
N66

We find that the equation is not balanced yet. As the number of hydrogen and oxygen atoms are unequal on the two sides. 

First balance the oxygen atom.

Step 6: If we multiply 2 in the product (in H2O) and 6, we will get the equal number of oxygen atoms on both sides.

No. of atoms of nitrogenReactant (in HNO3)Product (in H2SO4 + + 6NO+ H2O)
Initially1817
To balance184 + 12 + 2 x 1 = 18

Step 7: Write the resulting equation:

S + 6HNO3→ H2SO4 + 6NO2 + 2H2O

Step 8: Now check whether the equation is balanced or not by comparing the atoms.

Reactants (left side)Products (right side)
ElementNumber of atomsNumber of atoms
S11
H66
O1818
N66

Step 9: Write the resulting equation:

S + 6HNO3→ H2SO4 + 6NO2 + 2H2O

We find that the equation is balanced now.

Step 10: Write down the final balanced equation:

S + 6HNO3→ H2SO4 + 6NO2 + 2H2O



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