1.

Bond dissociation enthalpy of H_(2), CI_(2) and HCI are 434, 242 and 431 "kJ mol"^(-1) respectively. Enthalpy of formation of HCl is

Answer»

`93 "kJ mol"^(-1)`
`-245 "kJ mol"^(-1)`
`-93 "kJ mol"^(-1)`
`245 "kJ mol"^(-1)`

Solution :The REACTION for formation of HO can be written as
`H_(2) + CI_(2) to 2HCI`
`H- H + CI- CI to 2(H- CI)`
Substituting the given values, we GET enthalpy of formation of
`2HCI = - (862-676) = - 186` kJ
`therefore` Enthalpy of formation of
`HCI = (-186)/(2) "kJ"= -93` kJ


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