1.

By X-ray studies, the packing of atoms in a crystal of gold is found to be in layers such that starting from any layer, every fourth layer is found to be exactly identical . The density of gold is found to be 19.4 g cm^(-3) and its atomic mass is 197 a.m.u. The length of the edge of the unit cell will be

Answer»

407 pm
189 pm
814 pm
204 pm

Solution :`RHO=(ZxxM)/(a^3xxN_0xx10^(-30))`
or `a^3=(ZxxM)/(rhoxxN_0xx10^(-30))`
For ccp, i.e., f.c.c., Z=4.
HENCE,`a^3=(4xx197)/(19.4xx6.02xx10^23xx10^(-30))`
`=6.747xx10^7`
=`67.47xx10^6`
or `a=(67.47)^(1//3)xx10^2`
`=4.07xx10^2` pm
=407 pm


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