Calculale the d_((N-C)) in (CH_(3))_(3)N molecule by using Eqs. (1.18) and (1.19) above and show from which equation d_((N-C)) closely resembles with the experimental value of d_((M|N-C))=1.47 Å. (Given: r_(N) = 0.75 Å, r_(C ) = 0.77Å, chi_(A)=3.0, chi_(C )=2.5

Calculale the d_((N-C)) in (CH_(3))_(3)N molecule by using Eqs. (1.18)

1.	Calculale the d_((N-C)) in (CH_(3))_(3)N molecule by using Eqs. (1.18) and (1.19) above and show from which equation d_((N-C)) closely resembles with the experimental value of d_((M\|N-C))=1.47 Å. (Given: r_(N) = 0.75 Å, r_(C ) = 0.77Å, chi_(A)=3.0, chi_(C )=2.5
Answer» Solution : We get `d_(N - C) = r_(N) + r_(C) = (0.75 + 0.77) Å = 1.52 Å` we get `d_(N - C) = r_(N) + r_(C) - 0.09 (chi_(N) - chi_(C))` `= 0.75 + 0.77 - 0.09 (3.0 - 2.5)` `= 1.475 Å` The VALUE of `d_(N - C)` CLOSELY resembles the EXPERIMENTAL value.