Calculate Delta_(h)H^(ɵ) for the addition of 1 mol of H_2 to (i) benzene (C_(6)H_(6)) and (ii) 1,3-cyclohexadiene (C_(6)H_(8)) from frigure. Strategy (i): Target is to find Delta_(h)H^(ɵ) of the following reaction benzene +H_(2)to1,3-Cyclohexadiene Thus, look for the data involving these two compound. strategy (ii). We need to find Delta_(h)H^(ɵ) of the following reaction: 1,3-C_6H_8+H_2toC_6H_(12) Thus, we look for the data involving these two compounds.

Calculate Delta_(h)H^(ɵ) for the addition of 1 mol of H_2 to (i) benz

1.	Calculate Delta_(h)H^(ɵ) for the addition of 1 mol of H_2 to (i) benzene (C_(6)H_(6)) and (ii) 1,3-cyclohexadiene (C_(6)H_(8)) from frigure. Strategy (i): Target is to find Delta_(h)H^(ɵ) of the following reaction benzene +H_(2)to1,3-Cyclohexadiene Thus, look for the data involving these two compound. strategy (ii). We need to find Delta_(h)H^(ɵ) of the following reaction: 1,3-C_6H_8+H_2toC_6H_(12) Thus, we look for the data involving these two compounds.
Answer» Solution :(a). `C_(6)H_(6)+3H_2toC_(6)H_(12)`, `Delta_(h)H^(ɵ)=-208Kgmol^(-1)` (b). `1.3-C_6H_6+2H_2toC_6H_(12)`, `Delta_(h)H^(ɵ)=-232kJmol^(-1)` Substracting second equation (b) from the first (a), we get `C_6H_6+H_2to1,3-C_6H_6`, `Delta_(h)H^(ɵ)24kJmol^(-1)` (ii). (a). `1,3-C_6H_6+2H_2toC_6H_(12)toC_6H_(12)`, `Delta_(h)H^(ɵ)-232mol^(-1)` (b). `C_6H_(10)+H_(2)toC_6H_(12)`, `Delta_(h)H^(ɵ)-120kJmol^(-1)` SUBTRACTING second equation (b) from the first (a), we get `1,3-C_6H_8+H_2toC_6H_(10)`,`Delta_(h)H^(ɵ)112kJmol^(-1)`