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Calculate molarity of solution of ethanol in water in which the mole fraction of ethanol is 0.040 |
Answer» Let the mole fraction of ethanol (C2H5OH)\xa0be represented by x,Then the following expression represents its mole fraction in ethanol solution-\xa0xC2h5OH =\xa0{tex}\\frac{\\mathrm{n}\\left(\\mathrm{C}_{2} \\mathrm{H}_{5} \\mathrm{OH}\\right)}{\\mathrm{n}\\left(\\mathrm{C}_{2} \\mathrm{H}_{5} \\mathrm{OH}\\right)+\\mathrm{n}\\left(\\mathrm{H}_{2} \\mathrm{O}\\right)}{/tex}(where x\xa0C2H5OHrepresents mole fraction of ethanol)= 0.040 (given)....(i);where "n\'\' (represents number of moles of the two referred liquids in ethanol solution).The following steps are used for\xa0calculations,The aim is to find number of moles of ethanol in 1 L of the solution.Step 1 /- No. of moles in 1 L of water=\xa0{tex}\\frac{1000 \\mathrm \\ {g}}{18 \\mathrm \\ {g} \\mathrm \\ {mol}^{-1}}{/tex}= 55.55 molesStep 2 /-. Substituting n (H2O)= 55.55 in equation (i), we getx (\xa0C2H5OH)=\xa0{tex}\\frac{\\mathrm{n}\\left(\\mathrm{C}_{2} \\mathrm{H}_{5} \\mathrm{OH}\\right)}{\\mathrm{n}\\left(\\mathrm{C}_{2} \\mathrm{H}_{5} \\mathrm{OH}\\right)+55.55}{/tex}= 0.040......(given )solving for n (C2H5OH) we get,0.96 n ( C2\xa0H5\xa0OH )\xa0= 55.55\xa0{tex}\\times{/tex} 0.040{tex}\\therefore{/tex}\xa0n (C2H5OH)= 2.31 molsSo 2.31 moles of C2\xa0H5\xa0OH are present per litre of given ethanol solution.\xa0Hence,the\xa0molarity of the solution of ethanol is\xa02.31 M. | |