1.

Calculate the freezing point of a solution containing 60 g glucose (Molar mass = 180 g `mol^(-1)`) in 250 g of water . (`K_(f)` of water = `1.86 K kg mol^(-1)`)

Answer» `DeltaT_(f) = K_(f) xx m `
`T_(f)^(@) - T_(s) = (K_(f) xx W_(B))/(M_(B) xx W_(A) (kg))`
`T_(f)^(@)` for water = `0^(@)C = 273 K`
`M_(B) (C_(6)H_(12)O_(6)) = 12 xx 6 + 12 xx 1 + 6 xx 16 = 180 g//mol`
`273 - T_(s) = (1.86 xx 60 xx 1000)/(180 xx 250)`
`273-T_(s) = 2.48`
`T_(s) = 273 - 2.48`
`T_(s) = 270.52 K`
`{:(T_(f)^(@) = "freezing point of solvent") , (T_(s)^(@) = "freezing point of solution." ) , (W_(B) = "given mass of solute"), (M_(B) = "molar mass of solute") , (W_(A) = "mass of solvent") , (K_(f)= "mole depression constant"):}`


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