1.

Calculate the number of atoms present in 2 gram of crystal which has face-centred cubic (FCC) crystal lattice having edge length of 100 pm and density 10 g cm-3.

Answer»

Given: Density (d) = 10 g cm-3

Edge length (a) = 100 pm = 100×10–12 m = 100×1010 cm

Mass of crystal = 2 g

To find: Number of atoms

Formula: Density =\(\frac{Mass}{Volume}\)

Density=\(\frac{Mass}{Volume}\)

∴ Volume =\(\frac{Mass}{Density}\)

∴  Volume = \(\frac{2\,g}{10\,g\,cm^{-3}}=0.2\,cm^3\)

Volume of unit cell = a3 = (100×10–10 cm)3 = 1×10-24 cm3

Number of unit cells in 2 g of crystal =\(\frac{total\,volume}{volume\,of\,unit\,cell}\)

=\(\frac{0.2\,cm^3}{1\times10^{-24}cm^3}\)

= 0.2×1024 unit cells

∵ The given unit cell is of fcc type, therefore, it contains 4 atoms.

∴ 0.2×1024 unit cells will contain 4×0.2×1024 = 0.8×1024 atoms

= 0.8×1024 atoms = 8×1023 atoms

Ans: Number of atoms present in 2 g of given crystal is 8×1023 atoms.



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