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Calculate the percentage of ionic character of HF. Given that the dipole moment of HF is 1.91 D and its bonding length is 0.92Å. |
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Answer» Solution :If HF is 100% ionic, each atom would CARRY a charge equal to one unit, ie.., `4.8xx10^(-10)` esu. As the bond length of HF is 0.92 Å, itsdipoel moooment for 100% ionic CHARACTER would be `p_("ionic")=qxxd=4.8xx10^(-10)esuxx0.92xx10^(-8)CM` `=4.416xx10^(-18)esu*cm=4.416D` `[because 10^(-18)esu*cm=1D]` `therefore%` ionic character`=(mu_("observed"))/(mu_("ionic"))xx100=(1.91xx100)/(4.416)=43.25` |
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