1.

Calculate the percentage of ionic character of HF. Given that the dipole moment of HF is 1.91 D and its bonding length is 0.92Å.

Answer»

Solution :If HF is 100% ionic, each atom would CARRY a charge equal to one unit, ie.., `4.8xx10^(-10)` esu. As the bond length of HF is 0.92 Å, itsdipoel moooment for 100% ionic CHARACTER would be
`p_("ionic")=qxxd=4.8xx10^(-10)esuxx0.92xx10^(-8)CM`
`=4.416xx10^(-18)esu*cm=4.416D`
`[because 10^(-18)esu*cm=1D]`
`therefore%` ionic character`=(mu_("observed"))/(mu_("ionic"))xx100=(1.91xx100)/(4.416)=43.25`


Discussion

No Comment Found