1.

Calculate the pressure of 154 g carbon dioxide in a vessel of 2.0 L capacity at `30^(@)C`, a = 648 L bar atm `K^(-1) mol^(-1), b = 0.0427 L mol^(-1)`

Answer» a. `NH_(3)` will have larger value of a because of H bonding
b. `N_(2)` should have larger value of b because of larger molecular size.


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