1.

Calculate the temperature at which root mean square speed of SO2 molecules is the same as that of oxygen at 27°C

Answer»

The rms speed is related to the other variables such as temperature and molecular mass through

Vrms = sqrt(3 R T/M), where M is the molar mass of the gas, R the gas constant and T the ABSOLUTE temperature.

So if rms speeds are equal, then

T1/M1 = T2/M2

or

T1 = (M1/M2) T2

Now M1 (the molar mass of SO2) is 64.1 g/mole, whilst that of O2 is 32.0 grams/mole.

Therefore M1/M2 = 2, so the absolute temerature of SO2 should be twice that of the absolute temperature of O2.

So

T1 = 2 T2= 2 * (273 + 27) = 600 K

In Celsius that is 327 Celcius.



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