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Calculate the volume of air containing 21% oxygen by volume at STP, required in order to convert 294cm³ of sulphur dioxide to sulphur trioxide under the same conditions(FIITJEE Question). |
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Answer» Answer: The volume of the AIR with 21 % oxygen required to to convert 294cm³ of sulphur dioxide to sulphur trioxide is 700cm³ Explanation: The equation of the reaction of sulphur dioxide ( SO₂) and Oxygen (O₂) to form sulphur trioxide ( SO₃), is given below: 2SO₂ (G) + O₂ (g) ⇒ 2SO₃ (g) We can calculate the moles of SO₂ and use it to find the moles of O₂ required by using the equation We have 294 cm³ of SO₂, we can calculate the moles of the SO₂ by use of Avagadro's LAW Avagadros law state that 1 mole of any gas occupies exactly 22.4L by volume at STP. Having this in mind, let us convert 22.4 to litres 1000cm³ = 1 L Then 294 cm³ = 294cm³/1000 = 0.294L Convert 0.294L to moles: If 22.4L = 1 mole Then 0.294L = 1 mole × 0.294/22.4 = 0.013125 moles Use the mole ratio in the equation to find the moles of the oxygen required: Mole ratio of SO₂:O₂ is 2:1 Therefore the moles of the oxygen used is 0.013125/2 moles = 0.0065625moles This is the number of moles of oxygen from the equation: We will use the same Avagadro's law to find the volume of oxygen from the moles If 1 mole occupies 22.4 L Then 0.0065625 moles will occupy ⇒ 0.0065625moles × 22.4/1 mole = 0.147 Litre The amount of oxygen used up in this reaction is 0.147 litres or 147cm³. The next step is to calculate the amount of air that contains 147cm³ of oxygen ⇒ If 21% = 147cm³ Then 100% = 147 × 100/21 = 700cm³ Therefore the volume of air required is 700 cm³ |
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