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Carbylamine test is performed in alc . ` KOH` by heating a mixture of :A. Chloroform and silver powderB. Trihalogentaded methane and a primary amineC. An alkyl halide and a primary amineD. An alkyl cyanide and a primary amine |
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Answer» Correct Answer - `b` Carbylamine test is given by `1^(@)` amine with `CHCl_(3) + KOH` `RNH_(2) + CHCl_(3) + KOH rarr underset("Isocyanide")(R overset(o+)(N) -= overset(o-)(C)` It gives an offensicve smell of isovyanide. Mehcanism proceeds via carbene. `(:C Cl_(2))` or `(:CX_(2))` or `(:CXX^(1))` (`XX^(1) implies` Two different halogens) |
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