1.

Chlorination of methane does not occur in dark because

Answer»

methane can form FREE radicals in presence of sunlight ohnly
to get chlorine free radicals from `Cl_(2)` molecules ENERGY is REQUIRED. It cannot happen in dark
substitution reaction can take place only in sunlight and not in dark
termination step cannot take place in dark, it requires sunlight.

Solution :Chlorination of methane is free RADICAL substitution. To get chlorine free radical energy is required which is provided by sunlight to initiate the reaction.
`Cl_(2) overset(h upsilon)to Cl^(**)+Cl^(**)`


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