1.

Chlorine is used purify drinking water . Excess of chlorine is harmful . The excess of chlorine is removed by treating with sulphur dioxide . Present a balanced equation for this redox change taking place in water .

Answer»

Solution :The SKELETAL equation is :
`Cl_2(g) +SO_2(AQ) + H_2O(l) rarr Cl^(-) (aq) +SO_4^(2-) (aq)`
Reduction half equation :
`Cl_2(aq) rarr Cl^(-) (aq)`
Balancing Cl ATOMS
`Cl_2(aq) rarr 2Cl^(-) (aq)`
Balancing O. N. by adding electrons :
`overset0(Cl_2)(aq)+2e^(-)rarr2Cl^(-)(aq) ""...(i)`
Oxidation half equation :
`SO_2(aq) rarr SO_4^(2-)(aq)`
Balancing O.N. by adding electrons
`OVERSET(+4)(SO_2)(aq) rarr overset(+6"")(SO_4^(2-))(aq)+2e^(-)`
Balancing CHARGE adding `H^+` ions
`SO_2(aq) rarr SO_4^(2-) (aq) +2e^(-) +4H^(+)(aq)`
Balancing O atoms by adding `H_2O`
`SO_2(aq) +2H_2O(l) rarr SO_4^(2-) (aq) +2e^(-) +4H^(+) (aq) ""...(ii)`
Adding equations (i) and (ii) we gat
`Cl_2(aq) + SO_2(aq) +2H_2O(l) rarr 2Cl^(-)(aq) +SO_4^(2-) (aq) +4H^(+) (aq)`


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