1.

Chlorine is used to purify drinking water. Excess of chlorine is harmful. The excess of chlorine is removed by treating with sulphur dioxide. Present a balanced equation for this redox change taking place in water.

Answer»

Solution :GIVEN redox reaction….
`OVERSET(0)(Cl_(2(s)))+overset(+4)(SO_(2(AQ)))+H_(2)O_((l))tooverset(-1)(Cl_((aq))^(-))+overset(+6)(SO_(4(aq))^(-2))`
Half reaction …
O.H.R. : `overset(+4)(SO_(2(aq)))tooverset(+6)(SO_(4(aq))^(-2))`
R.H.R. : `overset(0)(Cl_(2(s)))tooverset(-1)(Cl_((aq))^(-))`
Balancing while adding electron.
O.H.R. : `SO_(2(aq))toSO_(4(aq))^(-2)+2e^(-)`
R.H.R. : `Cl_(2(s))+2e^(-)to2Cl_((aq))^(-)`
In O.H.R., balancing the H and O atom by `H_(2)O` and balancing according to MEDIUM and adding both the reaction.


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