1.

Chrome iron ore (x) was heated with dry `Na_(2)CO_(3)` in the presence of quick lime and air in a furnace. The mixture was extracted with water and filtered. The filtrate was yellow(A) which on adding conc. `H_(2)SO_(4)` turned to orange red. The solution was evaporated and cooled. The crystals of B were obtained. To the crystals in aqueous solution, `NH_(4)Cl` was added. On fractional crystallization, orange red crystals (C ) is formed. Compound (B) will beA. NaClB. `Na_(2)Cr_(2)O_(7)`C. `(NH_(4))_(2)Cr_(2)O_(7)`D. `NH_(4)Cl`

Answer» Correct Answer - B
`Na_(2)Cr_(2)O_(7)+2NH_(4)Clrarr(NH_(4))_(2)Cr_(2)O_(7)+2NaCl`
`(NH_(4))_(2)Cr_(2_)O_(7)` is less soluble than NaCl


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