1.

Classify each of the following substances into an acid or base or both and mention the concept/concepts on the basis of which you can do so. (i) HCl(aq) " " (ii) NH_(3)(g) " " (iii) Na_(2)CO_(3)(aq) " " (iv)CH_(3)CO OH(aq) (v)CO_(2)(g) " " (vi)BF_(3) " " (vii)Ag^(+) " " (viii)CN^(-) (ix)H_(2)O " " (x)H_(2)SO_(4) "(xi)" HCO_(3)^(-) "(xii)"SiF_(4)

Answer»

Solution :(i) HCL (aq) - Acid (ARRHENIUS conecpt and Bronsted - LOWRY concept)
(ii) `NH_(3)(g) `-Base (Bronsted concept and Lewis concept)
(iii) `Na_(2)CO_(3)(aq)`- Base (Bronsted concept)
(iv) `CH_(3)CO OH(aq)`-Acid (Arrhenius concept and Bronsted concept)
(V) `CO_(2)(g)`-Acid (Bronsted concept and Lewis concept)
(vi) `BF_(3)`-Acid (Lewis concept)
(vii) `Ag^(+)`- Acid (Lewis concept)
(viii) `CN^(-)`- Base (Lewis concept)
(ix) `H_(2)O`- Both acid and base, i.e., amphoteric (Bronsted concept)
(x) `H_(2)SO_(4)`-Both acid and base, i.e., amphoteric (Bronsted concept)
(xi) `CHO_(3)^(-)`-Both acid and base, i.e., amphoteric (Bronsted concept)
(xii) `SiF_(4) ` - Acid (Lewis concept), as silicon can expand its octet .


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