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Classify the following groups as ortho, para or meta directing when present on benzene nucleus. (i) -CH_(3),(ii)-NH_(2), (iii) -NO_(2), (iv)-COOH, (v) -OH, (vi) -SO_(3)H, (vii) -X("halogen"), (viii) OCH_(3), (ix) -CHO, (x) -CN (B) Classify the following goups as activating or deactivating with respect to further electrophilicsubstitution of the aromatic ring. (i) -NH_(2) (ii) -NO_(2) (iii) -SO_(3)H, (iv) -CH_(3) (v) -CI, (vi)-CN. ( C) For each of the following substituents indicate whether in donate electron or withdraw electron. |
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Answer» (i), (ii), (v), (vii) and (viii) meta-directing groups : (iii), (IV), (VI), (ix) and (x) Activating grups : (i) and (iv) Deacting groups : (ii), (iii), (v) and (vi) EDG : (ii), (v), and (viii) EWG : (i), (iii), (iv) and (vi) |
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